|  Journal of Physical and Chemical Reference Data 2014 , 43 (3) , 033102. Find NCBI SARS-CoV-2 literature, sequence, and clinical content: https://www.ncbi.nlm.nih.gov/sars-cov-2/. Find more information about Crossref citation counts. National Center for Biotechnology Information, Unable to load your collection due to an error, Unable to load your delegates due to an error. A. H. Pádua, J.-Y. Mohamed Raghibi, Baokou Xiong, Satyajit Phadke, Mérièm Anouti. The reaction rate constant between singlet oxygen and acetonitrile is reported to be 2.4 x 10-16 cm 3 molecule-1 sec-1 (Graedel, 1978); this predicts an atmospheric half-life of > 5000 years for acetonitrile. NIH Measurements on mixed acetone-N-methylformamide solvents showed that the solubility of oxygen does not vary with solvent composition in a predictable manner. Please enable it to take advantage of the complete set of features! Acrylonitrile and water are partly soluble in each other. George E. Romanos, Lawien F. Zubeir, Vlassis Likodimos, Polycarpos Falaras, Maaike C. Kroon, Boyan Iliev, Gabriela Adamova, and Thomas J. S. Schubert . Selective absorption of CO 2 from H 2 , O 2 and N 2 by 1-hexyl-3-methylimidazolium tris(pentafluoroethyl)trifluorophosphate. The dissolved oxygen content is found from the change in absorbance and the known 1:1 stoichiometry of addition of singlet oxygen to DPIBF. -ionic liquid systems: An experimental and modeling study. Stéphane Stevanovic, Ajda Podgoršek, Agilio A. H. Pádua, and Margarida F. Costa Gomes . Zhigang Lei, Chengna Dai, and Biaohua Chen . It is an aliphatic nitrile and a volatile organic compound. Sifting Ionic Liquids as Additives for Separation of Acetonitrile and Water Azeotropic Mixture Using the COSMO-RS Method. Phase Behaviour, Interactions, and Structural Studies of (Amines+Ionic Liquids) Binary Mixtures. Advances in Colloid and Interface Science. Epub 2020 May 26. Measurement and prediction. Mechanistic Insights into the Triplet Sensitized Photochromism of Diarylethenes. Effect of Acetonitrile on the Solubility of Carbon Dioxide in 1-Ethyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)amide, Laboratoire de Thermodynamique des Solutions et des Polymères, UMR 6003 CNRS/Université Blaise Pascal, Clermont-Ferrand, 24 avenue des Landais, 63177 Aubière Cedex, France. Xiao-Min Zhang, Kuan Huang, Shuang Xia, Yong-Le Chen, You-Ting Wu, Xing-Bang Hu. Suojiang Zhang, Qing Zhou, Xingmei Lu, Yuting Song, Xinxin Wang. J. N. Canongia Lopes, Margarida F. Costa Gomes, Pascale Husson, Agílio A. H. Pádua, Luis Paulo N. Rebelo, Sabine Sarraute, and Mohammad Tariq . This article is cited by Mixing scheme of an aqueous solution of tetrabutylphosphonium trifluoroacetate in the water-rich region. Density, Refractive Index, Interfacial Tension, and Viscosity of Ionic Liquids [EMIM][EtSO4], [EMIM][NTf2], [EMIM][N(CN)2], and [OMA][NTf2] in Dependence on Temperature at Atmospheric Pressure. Padua, M.F. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Chemistry. Xiankun Wu, Zilei Deng, Jiujuan Yan, Zhongyang Zhang, Feng Zhang, and Zhibing Zhang . The Hansen solubility parameters (HSPs) of oxygen were determined from the measured solubilities in the pure solvents. 2019 Aug;411(20):5287-5296. doi: 10.1007/s00216-019-01910-2. Jinlong Li, Xiaoqian Yang, Kexia Chen, Yeling Zheng, Changjun Peng, and Honglai Liu . Prediction of Henry's law constant of CO2 in ionic liquids based on SEP and Sσ-profile molecular descriptors. Effect of Water on the Carbon Dioxide Absorption by 1-Alkyl-3-methylimidazolium Acetate Ionic Liquids. the Altmetric Attention Score and how the score is calculated. The vapor pressures of the [C2mim][NTf2] + CH3CN mixtures were measured in the same temperature range, and strong negative deviations from Raoult's law were obtained:  up to 36% for a mixture with xCH3CN = 0.46 at 334 K. Negative excess molar volumes of approximately −1 cm3 mol-1 at equimolar composition could also be calculated from density measurements of the pure components and of the mixtures. A. H. Padua. Acetonitrile, often abbreviated MeCN (methyl cyanide), is the chemical compound with the formula CH 3 CN.This colourless liquid is the simplest organic nitrile (hydrogen cyanide is a simpler nitrile, but the cyanide anion is not classed as organic).It is produced mainly as a byproduct of acrylonitrile manufacture. Interactions of Fluorinated Gases with Ionic Liquids: Solubility of CF4, C2F6, and C3F8 in Trihexyltetradecylphosphonium Bis(trifluoromethylsulfonyl)amide. Ayako Nitta, Takeshi Morita, Keiko Nishikawa, Yoshikata Koga. QUILL Research Center, School of Chemistry and Chemical Engineering, Queen's University of Belfast, United Kingdom. USA.gov. E-mail:  [email protected]. The molecular characteristics dominating the solubility of gases in ionic liquids. L. Pison, J. N. Canongia Lopes, L. P. N. Rebelo, A. You have to login with your ACS ID befor you can login with your Mendeley account. Ramesh L. Gardas,, Mara G. Freire,, Pedro J. Carvalho,, Isabel M. Marrucho,, Isabel M. A. Fonseca,, Abel G. M. Ferreira, and. Costa Gomes. Zhigang Lei, Chengna Dai, and Biaohua Chen . The solubilities found, accurate to +/- 6%, for oxygen in air-equilibrated solvents, are (mM): acetone, 2.37; acetonitrile, 2.42; dimethylsulfoxide, 0.33; ethanol, 1.94; N-methylformamide, 1.31. Industrial & Engineering Chemistry Research 2014, 53 (23) , 9932-9937. Find more information about Crossref citation counts. The solubility of oxygen in 21 pure organic solvents was measured at 298.2 K and 101.33 kPa using the static method. Masaki Watanabe, Daisuke Kodama, Takashi Makino, Mitsuhiro Kanakubo. A photochemical method for determining the oxygen concentration in air-saturated non-aqueous solvents has been developed. It has a pungent odor of garlic or onions. This site needs JavaScript to work properly. Advantages of Ion-based Mole Fractions for Describing Phase Equilibria in Ionic Liquids: Application to Gas Solubility. Shaojuan Zeng, Xiangping Zhang, Lu Bai, Xiaochun Zhang, Hui Wang, Jianji Wang, Di Bao, Mengdie Li, Xinyan Liu, and Suojiang Zhang . Nanostructural Organization in Acetonitrile/Ionic Liquid Mixtures: Molecular Dynamics Simulations and Optical Kerr Effect Spectroscopy. Low-viscous fluorine-substituted phenolic ionic liquids with high performance for capture of CO2. Yu-Feng Hu, Zhi-Chang Liu, Chun-Ming Xu, Xian-Ming Zhang. We report the oxygen electro-reduction in air-saturated acetonitrile (MeCN) solution supported by 0.1 M tetra-n-butylammonium perchlorate salt under two experimental conditions: (1) anhydrous MeCN at elevated temperatures from 298.5 to 313.0 K on platinum electrodes; (2) water-mixed MeCN solution (mole fraction of MeCN: 0.72 < χ MeCN < 1) at 298.5 K on glassy carbon electrodes. Physicochemical Investigation of Adiponitrile-Based Electrolytes for Electrical Double Layer Capacitor. Effect of Fluorination and Size of the Alkyl Side-Chain on the Solubility of Carbon Dioxide in 1-Alkyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)amide Ionic Liquids. Prediction of Ionic Liquid Properties. Wen-Tao Zheng, Feng Zhang, You-Ting Wu, Xing-Bang Hu. O-O Bond Formation and Liberation of Dioxygen Mediated by N. The Adductomics of Isolevuglandins: Oxidation of IsoLG Pyrrole Intermediates Generates Pyrrole⁻Pyrrole Crosslinks and Lactams. Please reconnect. PρT Measurements of Imidazolium-Based Ionic Liquids. Molecular Solutes in Ionic Liquids: A Structural Perspective. The database contains over 29,000 line positions, chemical shifts, doublet splittings, and energy separations of photoelectron and Auger-electron lines. You’ve supercharged your research process with ACS and Mendeley! Zhigang Lei, Chengna Dai, Wei Wang, Biaohua Chen. Glucose Solvation by the Ionic Liquid 1,3-Dimethylimidazolium Chloride:  A Simulation Study. Thermodynamics and Micro Heterogeneity of Ionic Liquids. :  +33473407205. The gas solubility decreases with temperature, and the thermodynamic properties of solvation could be calculated. Khalil Parvaneh and Alireza Shariati . Effects of ionic liquid constituent cations, tetraalkylammoniums, on water studied by means of the “1-propanol probing methodology”. Low pressure methane solubility in lithium-ion batteries based solvents and electrolytes as a function of temperature. Experimental Investigation on the Solubility of Oxygen in Toluene and Acetic Acid. These metrics are regularly updated to reflect usage leading up to the last few days. The NIST XPS Database gives access to energies of many photoelectron and Auger-electron spectral lines. The solubilities found, accurate to +/- 6%, for oxygen in air-equilibrated solvents, are (mM): acetone, 2.37; acetonitrile, 2.42; dimethylsulfoxide, 0.33; ethanol, 1.94; N-methylformamide, 1.31. Epub 2012 Feb 6. High Throughput. Bi W, Jang GF, Zhang L, Crabb JW, Laird J, Linetsky M, Salomon RG. Chengna Dai, Zhigang Lei, Wei Wang, Li Xiao, Biaohua Chen. Evaluation of Gas Solubility Prediction in Ionic Liquids using COSMOthermX. Journal of Photochemistry and Photobiology A: Chemistry. The effect of the addition of acetonitrile on the solubility of carbon dioxide in an ionic liquid, the 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide, [C2mim][NTf2], was studied experimentally at pressures close to atmospheric and as a function of temperature between 290 and 335 K. It was observed that the solubility of carbon dioxide decreases linearly with the mole fraction of acetonitrile from a value of 2.6 × 10-2 in the pure ionic liquid at 303 K to a mole fraction of 1.3 × 10-2 in the mixture [C2mim][NTf2] + CH3CN with xCH3CN = 0.77 at the same temperature.